MEASUREMENTS OF ROTATIONAL ENERGY-TRANSFER AND QUENCHING IN OH A(2)SIGMA+,UPSILON(')=0 AT ELEVATED-TEMPERATURE

被引：36

作者：

LEE, MP

KIENLE, R

KOHSEHOINGHAUS, K

机构：

[1] DLR-Institut für Physikalische Chemie der Verbrennung, Stuttgart, D-70569

来源：

APPLIED PHYSICS B-LASERS AND OPTICS | 1994年 / 58卷 / 06期

关键词：

D O I：

10.1007/BF01081075

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Total rotational energy transfer rates have been measured at 1330 K for specific rotational levels in the OH A2SIGMA+, upsilon' = 0 state in collisions with H2O. Rotational levels ranging from N = 0 to 15 were studied. Measurements were performed in the post-flame region of a stoichiometric H-2/O2/He flame operating at 25 mbar. Quenching rates following excitation of individual upper rotational states were also measured. The RET and quenching rates both exhibit monotonic decreases with increasing rotational quantum number.

引用

页码：447 / 457

页数：11

共 50 条

[1] STATE-SPECIFIC ROTATIONAL ENERGY-TRANSFER IN OH (A2-SIGMA+, UPSILON' = 0) BY SOME COMBUSTION-RELEVANT COLLISION PARTNERS
JORG, A
MEIER, U
KIENLE, R
KOHSEHOINGHAUS, K
[J]. APPLIED PHYSICS B-PHOTOPHYSICS AND LASER CHEMISTRY, 1992, 55 (04): : 305 - 310
[2] ENERGY-TRANSFER IN A2SIGMA+ OH .1. ROTATIONAL
LENGEL, RK
CROSLEY, DR
[J]. JOURNAL OF CHEMICAL PHYSICS, 1977, 67 (05): : 2085 - 2101
[3] QUENCHING AND ROTATIONAL RELAXATION OF OH(A2SIGMA+ UPSILON' =O K')
KLEY, D
WELGE, KH
[J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (06): : 2870 - &
[4] A MODEL FOR TEMPERATURE-DEPENDENT COLLISIONAL QUENCHING OF OH A(2)SIGMA+
PAUL, PH
[J]. JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 1994, 51 (03): : 511 - 524
[5] QUENCHING AND ROTATIONAL TRANSFER RATES IN THE NU' = 0-MANIFOLD OF OH (A-2-SIGMA+
BURRIS, J
BUTLER, J
MCGEE, T
HEAPS, W
[J]. CHEMICAL PHYSICS, 1991, 151 (02) : 233 - 238
[6] LASER DOUBLE-RESONANCE MEASUREMENTS OF ROTATIONAL ENERGY-TRANSFER RATES IN HF(UPSILON=2)
COPELAND, RA
PEARSON, DJ
CRIM, FF
[J]. CHEMICAL PHYSICS LETTERS, 1981, 81 (03) : 541 - 546
[7] ROTATIONAL ENERGY-TRANSFER AND LIF TEMPERATURE-MEASUREMENTS
CROSLEY, DR
SMITH, GP
[J]. COMBUSTION AND FLAME, 1982, 44 (1-3) : 27 - 34
[8] STATE-TO-STATE ROTATIONAL ENERGY-TRANSFER IN OH (A2-SIGMA+, V' = 1)
KIENLE, R
JORG, A
KOHSEHOINGHAUS, K
[J]. APPLIED PHYSICS B-PHOTOPHYSICS AND LASER CHEMISTRY, 1993, 56 (05): : 249 - 258
[9] BRANCHING FRACTIONS OF THE PRODUCT NO(A(2)SIGMA(+), UPSILON=0, 1) AND NO(B(2)PI(R), UPSILON=0) EMISSIONS OBSERVED AS A FUNCTION OF UPSILON' IN THE ENERGY-TRANSFER REACTION N2(A(3)SIGMA(U)(+), UPSILON')+NO(X(2)PI(R), UPSILON''=0)
THOMAS, JM
KATAYAMA, DH
[J]. CHEMICAL PHYSICS LETTERS, 1993, 214 (02) : 250 - 256
[10] ROTATIONAL ENERGY-TRANSFER IN OH (A 2SIGMA+, V' = 0) - A METHOD FOR THE DIRECT DETERMINATION OF STATE-TO-STATE TRANSFER-COEFFICIENTS
JORG, A
MEIER, U
KOHSEHOINGHAUS, K
[J]. JOURNAL OF CHEMICAL PHYSICS, 1990, 93 (09): : 6453 - 6462

← 1 2 3 4 5 →