IMIDAZOLE DERIVATIVES .7. 2,3-DIHYDRO-1,3,4,5-TETRAMETHYL-2-METHYLEN-1H-IMIDAZOLE AS COUPLING REAGENT - THE X-RAY STRUCTURE OF BIS(1,3,4,5-TETRAMETHYL-2-IMIDAZOLYL)METHYLIUM IODIDE

被引:0
|
作者
KUHN, N
BOHNEN, H
KRATZ, T
HENKEL, G
机构
来源
关键词
IMIDAZOLES;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
2,3-Dihydro-1,2,3,4-tetramethyl-2-methylen-1H-imidazole (1) reacts with 1,3,4,5-tetramethyl-2-(methylthio)imidazolium iodide (4) in the presence of pyridine to give bis(1,3,4,5-tetra-methyl-2-imidazolyl)methylium iodide (5) which is also formed by the reaction of 4 and methyl lithium in the ratio 2:3. The X-ray structure of 5 is reported.
引用
收藏
页码:1149 / 1151
页数:3
相关论文
共 50 条
  • [41] 2-(4,5,6,7-tetrafluorobenzimidazol-2-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl, a hydrogen-bonded organic quasi-1D ferromagnet
    Murata, Hidenori
    Miyazaki, Yuji
    Inaba, Akira
    Paduan-Filho, Armando
    Bindilatti, Valdir
    Oliveira, Nei Fernandes, Jr.
    Delen, Zeynep
    Lahti, Paul M.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (01) : 186 - 194
  • [42] On rearrangements by cyclialkylations of arylpentanols to 2,3-dihydro-1H-indene derivatives.: Part 1.: An unexpected rearrangement by the acid-catalyzed cyclialkylation of 4-(2-chlorophenyl)-2,4-dimethylpentan-2-ol under formation of trans-4-chloro-2,3-dihydro-1,1,2,3-tetramethyl-1H-indene
    Blum, R
    Giovannini, E
    Hengartner, U
    Vallat, G
    HELVETICA CHIMICA ACTA, 2002, 85 (06) : 1827 - 1840
  • [43] SYNTHESIS AND STRUCTURE BY X-RAY-DIFFRACTION OF 3,12-DIHYDRO-3,3,6,12-TETRAMETHYL-7H-PYRANO[2,3-C]ACRIDIN7-ONE
    SMOLDERS, RR
    HANUISE, J
    LEPOINT, T
    VOGLET, N
    TINANT, B
    DECLERCO, JP
    VANMEERSSCHE, M
    TETRAHEDRON, 1984, 40 (24) : 5181 - 5184
  • [44] Synthesis of 2,2′-bis(1-(2-aryl)-1H-pyrazol-4-yl)-3,3,3′,3′-tetramethyl-3H,3′H-5,5′-biindoles and 2,7-bis(1-(3-aryl)-1H-pyrazol-4-yl)-1,1,6,6-tetramethyl-1,6-dihydroindolo[7,6-g]indoles
    Rashidi, Ahmad
    Baradarani, Mehdi M.
    Joule, John A.
    ARKIVOC, 2011, : 252 - 259
  • [45] 2-(4 prime -nitrenophenyl)4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-3 -oxide -1-oxyl: Photogeneration of a quartet state organic molecule with both localized and delocalized spins
    Lahti, Paul M.
    Esat, Burak
    Walton, Richard
    Journal of the American Chemical Society, 1998, 120 (20):
  • [46] STRUCTURE OF 2-TERT-BUTYLIMIDO-LAMBDA-4-THIO-3,4-DIHYDRO-3,3,5,8-TETRAMETHYL-1(2H)-NAPHTHALENONE
    SCHEPPER, L
    NIELSEN, K
    NORRESTAM, R
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (SEP): : 2940 - 2943
  • [47] Interaction of 1,5-disubstituted 3-methyl-2-oxo-2,3-dihydro- 1H-imidazole-4-carbonitriles with hydrogen sulfide
    S. A. Chumachenko
    O. V. Shablykin
    E. B. Rusanov
    V. S. Brovarets
    Chemistry of Heterocyclic Compounds, 2011, 47 : 807 - 810
  • [48] On rearrangements by cyclialkylations of arylpentanols to 2,3-dihydro-1H-indene derivatives.: Part 2.: An unexpected rearrangement by the acid-catalyzed cyclialkylation of 2,4-dimethyl-2-phenylpentan-3-ol under formation of trans-2,3-dihydro-1,1,2,3-tetramethyl-1H-indene
    Giovannini, E
    Hengartner, U
    Pasquier, P
    HELVETICA CHIMICA ACTA, 2002, 85 (06) : 1841 - 1849
  • [49] Crystal structure of 4,4-dimethyl-2-(trifluoromethyl)-4,5-dihydro-1H-imidazole, C6H9F3N2
    Said, A. Musa
    Warad, Ismail
    Alzahrani, O. Seraj
    Zarrouk, Abdelkader
    Lentz, Dieter
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2019, 234 (03): : 579 - 580
  • [50] Synthesis of Some New 1,3,4,5-tetrasubstituted-1H-imidazole-2(3H)-thiones Via a Facile One-Pot Three-Component Reaction in the Presence of Solvent and Heteropolyacids
    Shaker, Mohammad
    Davoodnia, Abolghasem
    Vahedi, Hooshang
    Lari, Jalil
    Roshani, Mina
    Mallaeke, Hassan
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2017, 54 (01) : 313 - 317