MASS ACCOMMODATION OF ANILINE, PHENOL AND TOLUENE ON AQUEOUS DROPLETS

被引：13

作者：

HEAL, MR ^{[1
]}

PILLING, MJ ^{[1
]}

TITCOMBE, PE ^{[1
]}

WHITAKER, BJ ^{[1
]}

机构：

[1] UNIV LEEDS,SCH CHEM,LEEDS LS2 9JT,W YORKSHIRE,ENGLAND

来源：

GEOPHYSICAL RESEARCH LETTERS | 1995年 / 22卷 / 22期

关键词：

D O I：

10.1029/95GL02944

中图分类号：

P [天文学、地球科学];

学科分类号：

07 ;

摘要：

Mass accommodation coefficients on aqueous droplets have been measured for two substituted aromatic compounds using a droplet train apparatus and detection in the gas phase by laser induced fluorescence. Values of (1.8+/-0.5) x 10(-2) and (2.7+/-0.5) x 10(-2) have been obtained at 283 K for aniline and phenol, respectively. Mass accommodation of toluene was below the limit of detection of 1.0 x 10(-3). Phenol and aniline are chosen as models for polar and oxygenated species formed as C-y intermediates in the oxidation of less soluble aromatic hydrocarbon precursors. The measurements indicate that mass accommodation of such species could be a significant pathway for the removal of tropospheric hydrocarbons.

引用

页码：3043 / 3046

页数：4

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