POLYCONDENSATION KINETICS OF POLY(PHENYLENE ETHER SULFONE)

被引：5
|
作者：
YU, TY [1 ]
FU, SK [1 ]
LI, SJ [1 ]
JI, CG [1 ]
CHENG, WZ [1 ]
机构：
[1] FUDAN UNIV,INST MAT SCI,SHANGHAI,PEOPLES R CHINA
来源：
POLYMER | 1984年 / 25卷 / 09期
关键词：
CHEMICAL REACTIONS - Reaction Kinetics - MATHEMATICAL TECHNIQUES - MONOMERS - Chemistry - POLYETHERS - POLYMERIZATION - Condensation Reactions;
D O I：
10.1016/0032-3861(84)90392-6
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Data are presented which show that the synthesis of poly(phenyl ether sulphone) (from the potassium salts of 4,4 prime -dihydroxydiphenyl sulphone and 4,4 prime -dichlorodiphenyl sulphone or 4-chloro-4 prime -hydroxydiphenyl sulphone) was found to have different reaction kinetics according to the route used. By discriminating between rate constants (between monomer/monomer, monomer/polymer, polymer/polymer) a set of multi-parameter kinetic equations is obtained. Experimental and simulated values of the individual rate constants were in good agreement (for both the reaction rate and molecular weight distribution). The polycondensation reaction can be analyzed, in terms of the component reactions.
引用
收藏
页码：1363 / 1366
页数：4
相关论文
共 50 条
  • [21] Synthesis of poly(ether sulfone)s by self-polycondensation of AB-type monomers
    Matsumoto, Kazuya
    Komuro, Hitoshi
    Kai, Takuya
    Jikei, Mitsutoshi
    POLYMER JOURNAL, 2013, 45 (09) : 909 - 914
  • [22] POLYMERIZATION BLENDING FOR COMPATIBLE POLY(ETHER SULFONE)/ARAMID BLENDS BASED ON POLYCONDENSATION OF N-SILYLATED M-PHENYLENEDIAMINE WITH ISOPHTHALOYL CHLORIDE IN POLY(ETHER SULFONE) SOLUTION
    HAYASHI, H
    KAKIMOTO, M
    IMAI, Y
    POLYMER, 1995, 36 (14) : 2797 - 2805
  • [23] POLY(P-PHENYLENE SULFONE)
    ROBELLO, DR
    ULMAN, A
    URANKAR, EJ
    MACROMOLECULES, 1993, 26 (25) : 6718 - 6721
  • [24] Synthesis of poly(ether sulfone)s by self-polycondensation of AB-type monomers
    Matsumoto, Kazuya
    Komuro, Hitoshi
    Kai, Takuya
    Jikei, Mitsutoshi
    Polymer Journal, 2013, 45 (09): : 909 - 914
  • [25] Synthesis of poly(ether sulfone)s by self-polycondensation of AB-type monomers
    Kazuya Matsumoto
    Hitoshi Komuro
    Takuya Kai
    Mitsutoshi Jikei
    Polymer Journal, 2013, 45 : 909 - 914
  • [26] Novel soluble aromatic poly(ether amide sulfone amide ether ketone ketone)s by electrophilic solution polycondensation
    Ding, Nengwen
    Chen, Mengfei
    Cai, Mingzhong
    HIGH PERFORMANCE POLYMERS, 2011, 23 (02) : 132 - 140
  • [27] Non-isothermal crystallization kinetics of poly(ether sulfone) functionalized graphene reinforced poly(ether ether ketone) composites
    Yu, Fei
    Xiao, Linghan
    POLYMER TESTING, 2021, 97
  • [28] Reactive reinforcement of the interface of poly(ether sulfone)/poly(phenylene sulfide) polymer blend by PMR-POI
    Lai, MF
    Yang, YM
    Liu, JJ
    JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 85 (06) : 1297 - 1306
  • [29] Synthesis of copolymers of poly(ether sulfone ether ketone ketone) and poly(ether ketone diphenyl ketone ether ketone ketone) by electrophilic Friedel-Crafts solution polycondensation
    Cai, Mingzhong
    Zhu, Meihua
    Xiao, Fen
    Ding, Nengwen
    Song, Caisheng
    POLYMERS FOR ADVANCED TECHNOLOGIES, 2011, 22 (02) : 254 - 261
  • [30] Thermally crosslinkable poly(phenylene sulfide)/poly (ether sulfone)/polymerization of monomer reactant-polyimide blends
    Lai, MF
    Yang, YM
    Liu, JJ
    JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 83 (13) : 2906 - 2914
12345