STUDIES ON THE REACTIONS OF TRANSITION-METAL HYDRIDES WITH HETEROCUMULENES .6. REACTION OF CP2ZR(H)CL WITH RNCS (R=C6H5, 2-C10H7, C-C6H11 AND N-C4H9)

被引：5
|
作者：
WANG, M
LU, SW
BEI, MZ
GUO, HF
JIN, ZS
机构：
[1] ACAD SINICA,DALIAN INST CHEM PHYS,DALIAN 116012,PEOPLES R CHINA
[2] ACAD SINICA,CHANGCHUN INST APPL CHEM,CHANGCHUN 130000,PEOPLES R CHINA
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 447卷 / 02期
关键词：
D O I：
10.1016/0022-328X(93)80243-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The novel NS-containing zirconacycle complexes Cp2ZrCl[SC(H)NR] (1a, R = C6H5; 1b, R = 2-C10H7; 1c, R= C-C6H11; 1d; R = n-C4H9) were obtained by insertion reactions of Cp2Zr(H)Cl with RNCS. 1(a-d) could react further with Cp2Zr(H)Cl to yield a sulphur-bridging compleX (Cp2ZrCl)2S (2) and a Schiff base RN=CH2. The crystal structure of la has been determined by X-ray analysis.
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页码：227 / 231
页数：5
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