PREPARATIVE AND VIBRATIONAL SPECTROSCOPIC STUDIES OF ANILINIUM SALTS CONTAINING THE [HG2CL6]2-, [HG2CL4X2]2-, [CDHGI6]2-, [CDHGI4BR2]2- AND [CDHGBR4I2]2- IONS (X = BR, I)

被引：0

作者：

ZAFIROPOULOS, TF ^{[1
]}

PLAKATOURAS, JC ^{[1
]}

PERLEPES, SP ^{[1
]}

机构：

[1] UNIV IOANNINA,DEPT CHEM,IOANNINA,GREECE

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1991年 / 46卷 / 11期

关键词：

TRIHALOGENOMERCURATES; CADMIUM(II)-MERCURY(II) HETERO-DINUCLEAR COMPLEXES; IR SPECTRA; RAMAN SPECTRA;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthetic procedures are described that allow access to anilinium salts containing the complex anions [Hg2Cl6]2-, [Hg2Cl4X2]2- (X = Br, I), [CdHgI6]2-, [CdHgI4Br2]2- and [CdHgBr4I2]2-. Isolated dimeric structures are proposed for the new complexes in the solid state, using X-ray powder patterns, Far-IR and Raman spectra. The spectral detail is greatly enhanced in measurements at low temperature (approximately 100 K).

引用

页码：1532 / 1538

页数：7

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