THE SYNTHESIS AND CHARACTERIZATION OF URIDINE 5'-(BETA-L-RHAMNOPYRANOSYL DIPHOSPHATE) AND ITS ROLE IN THE ENZYMATIC-SYNTHESIS OF RUTIN

被引：19

作者：

BARBER, GA ^{[1
]}

BEHRMAN, EJ ^{[1
]}

机构：

[1] OHIO STATE UNIV,DEPT BIOCHEM,484 W 12TH AVE,COLUMBUS,OH 43210

来源：

ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS | 1991年 / 288卷 / 01期

关键词：

D O I：

10.1016/0003-9861(91)90190-T

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Uridine 5′-(β-l-rhamnopyranosyl diphosphate) was synthesized by the condensation of uridine 5′-diphenylpyrophosphate and β-l-rhamnopyranosyl phosphate. That sugar 1-phosphate was made via the phosphitylation of the hemiacetal hydroxyl group of 2,3,4-tetra-O-acetyl-β-l-rhamnopyranose. An enzyme preparation from the primary leaves of mung bean (Phaseolus aureus) was shown to catalyze the transfer of l-rhamnose from UDP-β-l-rhamnose to the flavonol d-glucoside isoquercitrin to form rutin. © 1991.

引用

页码：239 / 242

页数：4

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