2-DIMENSIONAL DOMAIN SHAPE TRANSITIONS IN PHOTOSENSITIVE MONOLAYER ASSEMBLIES

被引:0
|
作者
YONEYAMA, M
FUJII, A
MAEDA, S
MURAYAMA, T
机构
[1] Mitsubishi Kasei Corporation, Research Center, Midori-ku, Yokohama, 227
关键词
LANGMUIR MONOLAYER; 2-DIMENSIONAL DOMAIN; PORPHYRIN; SPIROPYRAN;
D O I
10.1016/0303-2647(94)01496-T
中图分类号
Q [生物科学];
学科分类号
07 ; 0710 ; 09 ;
摘要
Bubble-stripe shape transitions of gaseous domains are observed in Langmuir monolayers of porphyrin/arachidic acid and porphyrin/spiropyran mixtures using fluorescence microscopy. Characteristics of the transition such as critical bubble size are found to be controllable by subphase pH or UV/visible irradiation. These features are discussed in terms of a balance between dipolar repulsions and line tension in the monolayer.
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页码:113 / 116
页数:4
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