A NEW TYPE OF SOLID-STATE CRYSTALLINE PHOTOPOLYMERIZATION

被引：2
|
作者：
XIAOLIN, Z
YOUAN, M
机构：
[1] Department of Material and Applied Chemistry, Changsha Institute of Technology, Changsha, Hunan
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 1990年 / 39卷 / 03期
关键词：
D O I：
10.1002/app.1990.070390309
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A new type of solid‐state crystalline photopolymerization is researched in which, different from the topochemical polymerization, vinyl monomers are filmed under the induction of other macromolecular compound, crystallized, and polymerized after photoirradiation. Therefore, it may be also known as induction‐filming polymerization. The crystalline polyacrylamide film with large spherulite structures was obtained from the crystalline acrylamide by this means. Microscopy, differential scanning colorimetry, and infrared measurements were carried out. Mechanism is proposed for the induction‐filming polymerization involved. Copyright © 1990 John Wiley & Sons, Inc.
引用
收藏
页码：583 / 589
页数：7
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