THE STRUCTURE OF THE SURFACE METHOXY SPECIES ON NI(111)

被引:31
|
作者
SCHAFF, O
HESS, G
FRITZSCHE, V
FERNANDEZ, V
SCHINDLER, KM
THEOBALD, A
HOFMANN, P
BRADSHAW, AM
DAVIS, R
WOODRUFF, DP
机构
[1] MAX PLANCK GESELL, FRITZ HABER INST, D-14195 BERLIN, GERMANY
[2] UNIV WARWICK, DEPT PHYS, COVENTRY CV4 7AL, W MIDLANDS, ENGLAND
关键词
ALKOXIDES; CHEMISORPTION; COPPER; PHOTOELECTRON DIFFRACTION; SINGLE CRYSTAL SURFACES; SOLID-GAS INTERFACES; SURFACE STRUCTURE;
D O I
10.1016/0039-6028(95)00202-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Using photoelectron diffraction in the scanned energy mode the structure of the surface methoxy species (CH3O-) on Ni{111} has been determined. Bonding occurs at the "fcc" threefold symmetric hollow site with a Ni-O bond length of 1.94 Angstrom; the O-C axis is perpendicular to the surface.
引用
收藏
页码:201 / 206
页数:6
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