PHTHALIMIDESULFENYL CHLORIDE .4. ADDITION TO ACETYLENES AND SYNTHETIC UTILIZATION OF THEIR ADDUCTS

被引：27

作者：

CAPOZZI, G

GORI, L

MENICHETTI, S

NATIVI, C

机构：

[1] Centro C.N.R. 'Chimica e Struttura dei Composti Eterociclici e loro Applicazioni', Dipartimento di Chimica Organica, Universita' di Firenze, I-50121, Firenze

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1992年 / 15期

关键词：

D O I：

10.1039/p19920001923

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Both the stereo- and regio-chemical reactivity of the phthalimidesulfenyl chloride 1 towards symmetrical and terminal acetylenes and the reactivity of the adducts 3 and 5 with various nucleophiles has been investigated. Nucleophilic substitution of the phthalimide residue was achieved with MeLi, PhLi, Bu(t)Li, (Me3Si)2NNa and Me3SiSMe. The synthesis of beta-chlorovinyl tributylstannyl sulfides 14. is also described. The synthetic potential of the new sulfur compounds is discussed.

引用

页码：1923 / 1928

页数：6

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