OXIDATION OF 2-ETHYLHEXANAL IN THE LIQUID-PHASE .1. NONCATALYTIC PATHWAY

被引：10
|
作者：
GLINSKI, M [1 ]
KIJENSKI, J [1 ]
机构：
[1] TECH UNIV WARSAW,POLITECH,FAC CHEM,CATALYT SYNTH LAB,PL-00662 WARSAW,POLAND
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1995年 / 55卷 / 02期
关键词：
D O I：
10.1007/BF02073065
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The liquid phase oxidation of 2-ethylhexanal with oxygen in a flow system has been studied at 303.2-355.7 K. 2-Ethylhexanoic acid was found to be the main reaction product. As side-products: 3-heptyl formate, 3-heptanol, 3-heptanone, and heptane were detected. The influence of oxygen to reactant molar ratio and temperature on the reaction selectivity was investigated. The maximum yield of acid was 67.4% at a selectivity of 71.4%.
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页码：311 / 318
页数：8
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