HETERO-DIELS-ALDER ADDITIONS OF SULFUR-DIOXIDE TO 1,3-DIENES - A PROPOSAL FOR A NEW REACTIVE DIENE FROM AB-INITIO CALCULATIONS

被引：6

作者：

SUAREZ, D ^{[1
]}

IGLESIAS, E ^{[1
]}

SORDO, TL ^{[1
]}

SORDO, JA ^{[1
]}

机构：

[1] UNIV OVIEDO,DEPT QUIM FIS & ANALIT,E-33006 OVIEDO,SPAIN

来源：

TETRAHEDRON | 1995年 / 51卷 / 46期

关键词：

D O I：

10.1016/0040-4020(95)00806-J

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ab initio calculations suggest that 1-methoxy-1,3-cyclohexadiene can be used to get a sultine when reacting with sulfur dioxide via a Diels-Alder reaction. The Cheletropic reaction (leading to a sulfolene) does net compete with the Diels-Alder cycloaddition either kinetically or thermodynamically.

引用

页码：12661 / 12666

页数：6

共 31 条

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