FLUORINATED ALUMINA AS A CATALYST FOR SKELETAL ISOMERIZATION OF N-BUTENE

被引：37
|
作者：
CHENG, ZX [1 ]
PONEC, V [1 ]
机构：
[1] LEIDEN UNIV,GORLAEUS LABS,2300 RA LEIDEN,NETHERLANDS
来源：
APPLIED CATALYSIS A-GENERAL | 1994年 / 118卷 / 02期
关键词：
ALKENE; ALUMINA (MODIFIED); BRONSTED ACID SITES; ISOMERIZATION (SKELETAL); LEWIS ACID SITES;
D O I：
10.1016/0926-860X(94)80308-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Alumina modified by various fluorine containing compounds has been studied in reactions of n-butene. Combination of the results thus obtained with pieces of information from the literature leads to the following model. Skeletal isomerization takes place on Lewis acid sites as a monomolecular conversion, while on a catalyst with Bronsted acid sites the bimolecular mechanism can prevail. Experiments with higher alkenes support this picture.
引用
收藏
页码：127 / 138
页数：12
相关论文
共 50 条
  • [41] The role of the acid strength of the catalysts in the skeletal isomerisation of n-butene
    Houzvicka, J
    Nienhuis, JG
    Ponec, V
    APPLIED CATALYSIS A-GENERAL, 1998, 174 (1-2) : 207 - 212
  • [42] Formation and Regeneration of Shape-Selective ZSM-35 Catalysts for n-Butene Skeletal Isomerization to Isobutene
    Xu, Quan
    Yang, Wenjing
    Chen, Zhiwei
    Ye, Yingchun
    Luo, Yan
    Street, Jason
    Zhou, Hongjun
    Xu, Chunming
    ACS OMEGA, 2018, 3 (07): : 8202 - 8211
  • [43] In situ FT-IR study on the reaction path of skeletal isomerization of n-butene over different zeolites
    Ivanov, P
    Papp, H
    APPLIED SURFACE SCIENCE, 2001, 179 (1-4) : 234 - 239
  • [44] Effect of partial NH4+ exchange on n-butene skeletal isomerization catalytic performance of FER zeolites
    Zhou, Feng
    Chen, Ming
    Zhang, Shumei
    Qiao, Kai
    Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section), 2012, 28 (06): : 927 - 932
  • [45] Modification of non-template synthesized ferrierite/ZSM-35 for n-butene skeletal isomerization to isobutylene
    Xu, WQ
    Yin, YG
    Suib, SL
    Edwards, JC
    OYoung, CL
    JOURNAL OF CATALYSIS, 1996, 163 (02) : 232 - 244
  • [46] Seed-solution-induced Synthesis of FER Zeolite and Its Catalytic Application in the Skeletal Isomerization of n-Butene
    Fan Jinlong
    Yang Fan
    Zhu Xuedong
    Xu Yarong
    Chen Lantian
    China Petroleum Processing & Petrochemical Technology, 2023, 25 (04) : 61 - 73
  • [47] Comparative study of the catalytic properties of ferrierite zeolite exchanged with alkaline earth metals in the skeletal isomerization of n-butene
    Cañizares, P
    Carrero, A
    CATALYSIS LETTERS, 2000, 64 (2-4) : 239 - 246
  • [48] Seed-solution-induced Synthesis of FER Zeolite and Its Catalytic Application in the Skeletal Isomerization of n-Butene
    Jinlong, Fan
    Fan, Yang
    Xuedong, Zhu
    Yarong, Xu
    Lantian, Chen
    CHINA PETROLEUM PROCESSING & PETROCHEMICAL TECHNOLOGY, 2023, 25 (04) : 61 - 73
  • [49] Synthesis of Nano-Hierarchical Ferrierite with Sole Template and Its Catalytic Application in n-Butene Skeletal Isomerization
    Liu, Wen
    Hu, Haiqiang
    Ke, Ming
    Liu, Yang
    Zhang, Lei
    Xia, Chengjie
    Wang, Qi
    CHEMISTRYSELECT, 2019, 4 (34): : 9972 - 9977
  • [50] The role of the density of active sites in skeletal isomerisation of n-butene
    Houzvicka, J
    Klik, R
    Kubelkova, L
    Ponec, V
    APPLIED CATALYSIS A-GENERAL, 1997, 150 (01) : 101 - 114
12345