THE 2ND DIELECTRIC VIRIAL-COEFFICIENT OF ASYMMETRICAL POLAR HARD DUMBBELL FLUIDS

被引：1
|
作者：
OHBA, M [1 ]
NOMURA, H [1 ]
机构：
[1] NAGOYA UNIV,SCH ENGN,DEPT CHEM ENGN,CHIKUSA KU,NAGOYA,AICHI 464,JAPAN
来源：
MOLECULAR PHYSICS | 1990年 / 70卷 / 04期
关键词：
D O I：
10.1080/00268979000102691
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We have calculated the second dielectric virial coefficient BΣ of some asymmetrical polar hard dumb-bell fluids. In the case of molecules with a short bond length, the effect of the asymmetry of molecular shapes is to increase BΣ. In contrast, for molecules with a long bond length, the effect is to decrease BΣ gradually. © 1990 Taylor & Francis Ltd.
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页码：729 / 733
页数：5
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