THE 2ND DIELECTRIC VIRIAL-COEFFICIENT OF ASYMMETRICAL POLAR HARD DUMBBELL FLUIDS

被引:1
|
作者
OHBA, M [1 ]
NOMURA, H [1 ]
机构
[1] NAGOYA UNIV,SCH ENGN,DEPT CHEM ENGN,CHIKUSA KU,NAGOYA,AICHI 464,JAPAN
关键词
D O I
10.1080/00268979000102691
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have calculated the second dielectric virial coefficient BΣ of some asymmetrical polar hard dumb-bell fluids. In the case of molecules with a short bond length, the effect of the asymmetry of molecular shapes is to increase BΣ. In contrast, for molecules with a long bond length, the effect is to decrease BΣ gradually. © 1990 Taylor & Francis Ltd.
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页码:729 / 733
页数:5
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