THE SYNTHESIS OF BENZYLPHOSPHINE OXIDES VIA VICARIOUS NUCLEOPHILIC-SUBSTITUTION OF HYDROGEN

被引：21
|
作者：
LAWRENCE, NJ [1 ]
LIDDLE, J [1 ]
JACKSON, DA [1 ]
机构：
[1] ZENECA, DEPT PROC TECHNOL, HUDDERSFIELD HD2 1FF, W YORKSHIRE, ENGLAND
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 46期
基金：
英国工程与自然科学研究理事会;
关键词：
D O I：
10.1016/0040-4039(95)01744-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A range of substituted nitrobenzenes react with the anion of choromethyldiphenylphosphinoyl oxide to give the substituted nitrobenzyldiphenylphosphine oxide by vicarious nucleophilic substitution. The novel stereoselective synthesis of E-stilbenes via a one-pot vicarious nucleophilic substitution/Horner-Wittig reaction is described.
引用
收藏
页码：8477 / 8480
页数：4
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