THE SYNTHESIS OF BENZYLPHOSPHINE OXIDES VIA VICARIOUS NUCLEOPHILIC-SUBSTITUTION OF HYDROGEN

被引：21

作者：

LAWRENCE, NJ ^{[1
]}

LIDDLE, J ^{[1
]}

JACKSON, DA ^{[1
]}

机构：

[1] ZENECA, DEPT PROC TECHNOL, HUDDERSFIELD HD2 1FF, W YORKSHIRE, ENGLAND

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 46期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/0040-4039(95)01744-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A range of substituted nitrobenzenes react with the anion of choromethyldiphenylphosphinoyl oxide to give the substituted nitrobenzyldiphenylphosphine oxide by vicarious nucleophilic substitution. The novel stereoselective synthesis of E-stilbenes via a one-pot vicarious nucleophilic substitution/Horner-Wittig reaction is described.

引用

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页码：8477 / 8480

页数：4

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