COMPOSITION OF PHASE-DECOMPOSITION PRODUCTS IN FE-28CR-5NI ALLOY DETERMINED BY MOSSBAUER-SPECTROSCOPY

被引:6
|
作者
KUWANO, H [1 ]
ISHIKAWA, Y [1 ]
YOSHIMURA, T [1 ]
HAMAGUCHI, Y [1 ]
机构
[1] HITACHI LTD, MECH ENGN RES LAB, TSUCHIURA, JAPAN
关键词
MOSSBAUER EFFECT; ALPHA' PHASE; PHASE DECOMPOSITION; DUPLEX STAINLESS STEEL; ISOMER SHIFT; INTERNAL MAGNETIC FIELD; IRON-CHROMIUM-NICKEL ALLOY;
D O I
10.2320/jinstmet1952.57.2_141
中图分类号
学科分类号
摘要
The effect of Ni on the internal magnetic field and the isomer shift of Fe-57 in Fe-Cr alloys containing 3 to 14 at % Cr and 70 to 90 at % Cr were examined at room temperature by Mossbauer spectroscopy. A model Fe-28%Cr-5%Ni alloy was aged up to 5000 h at 723 K to investigate the phase decomposition of ferrite in a commercial duplex stainless steel. The alloy finally decomposed into a Cr-rich phase (alpha') and an Fe-rich phase (alpha) after aging. A paramagnetic absorption peak due to the alpha' phase has an isomer shift of -0.110 mm/s at room temperature. The value corresponds to a Cr content of 85(+/-1)at%Cr. The composition of the alpha phase was estimated to be 11(+/-1)at%Cr from the average internal magnetic field and the internal field distribution curve. The result of alpha phase was consistent with a result obtained by atom probe microanalysis. The latter underestimated the Cr content of the alpha' phase in comparison with the Mossbauer effect.
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页码:141 / 146
页数:6
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