THE STRUCTURE AND SPECTROSCOPY OF H-BONDED BENZOXAZOLE DERIVATIVES

被引：5
|
作者：
MORDZINSKI, A [1 ]
NOWAK, MJ [1 ]
LIPKOWSKI, J [1 ]
机构：
[1] POLISH ACAD SCI,INST PHYS,PL-02668 WARSAW,POLAND
来源：
JOURNAL OF MOLECULAR STRUCTURE | 1990年 / 219卷
关键词：
D O I：
10.1016/0022-2860(90)80057-Q
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two H-bonded systems: o-hydroxyphenylbenzoxazole and 3,6-(2-benzoxazolyl)-pyrocatechol were studied by means of IR spectroscopy in various environments: the isolated molecules in Ar matrices, "amorphous" (disordered) phase and the crystal layers. The results were discussed together with the X-ray crystal structure data and the photophysical behaviour of the systems. It is shown that the physical state of the sample controls the formation of the rare tautomeric and/or rotameric species in the ground state. © 1990.
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页码：209 / 214
页数：6
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