CU-63 AND AG-109 NMR-STUDIES OF COPPER(I) AND SILVER(I) SALTS IN MIXED-SOLVENTS CONTAINING NITRILES

被引：36

作者：

GILL, DS ^{[1
]}

RODEHUSER, L ^{[1
]}

RUBINI, P ^{[1
]}

DELPUECH, JJ ^{[1
]}

机构：

[1] UNIV NANCY 1,ETUDES SYST ORGAN & COLLOIDAUX LAB,CNRS,URA 406,F-54506 VANDOEUVRE NANCY,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1995年 / 91卷 / 15期

关键词：

D O I：

10.1039/ft9959102307

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The solvation of copper(I) in mixed solvent systems containing acetonitrile or benzonitrile and the co-solvents propionitrile, butyronitrile, valeronitrile, as well as trimethyl-, triethyl- and tributyl-phosphite has been examined by Cu-63 NMR and also, in the case of the phosphites, by P-31 NMR. The concentration dependence and the variation of the chemical shift of the silver-109 signal with solvent composition have been studied in solutions of silver trifluoroacetate (AgO2CCF3).

引用

页码：2307 / 2312

页数：6

共 45 条

[31] H-1 AND INEPT N-15 AND AG-109 NMR-STUDIES OF THE STRUCTURAL AND DYNAMIC FEATURES IN SOLUTION OF SOME SILVER(I) AND COPPER(I) COMPLEXES WITH POLYDENTATE N-4-DONOR LIGANDS, (R,S)-1,2-(6-R-PY-2-CH=N)2CY AND 1,2-(6-R-PY-2-CH=N)2ET (CY = CYCLOHEXANE, ET = ETHANE, R = H OR ME)
VANSTEIN, GC
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VRIEZE, K
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INORGANIC CHEMISTRY, 1984, 23 (25) : 4269 - 4278
[32] STRUCTURAL INVESTIGATIONS OF SILVER(I) AND COPPER(I) COMPLEXES WITH NEUTRAL N-4 DONOR LIGANDS - X-RAY CRYSTAL AND MOLECULAR-STRUCTURE OF THE DIMER [AG2(MU-(R,S)-1,2-(PY-2-CH=N)2CY)2](O3SCF3)2 AND H-1,C-13, AND INEPT AG-109 AND N-15 NMR SOLUTION STUDIES
VANSTEIN, GC
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[33] DINUCLEAR SILVER(I) AND COPPER(I) COMPLEXES WITH NEUTRAL N2S2 DONOR LIGANDS AND THEIR REACTIVITIES TOWARDS CO - STRUCTURES IN SOLUTION (H-1 AND INEPT AG-109 NMR) AND IN THE SOLID (X-RAY) OF [AG2(MU-(R)(S)-1,2-(THIOPHENE-2-CH=N)2-CYCLOHEXANE)2](O3SCF3)2H
VANSTEIN, GC
VANKOTEN, G
BLANK, F
TAYLOR, LC
VRIEZE, K
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SCHREURS, AMM
KOJICPRODIC, B
BREVARD, C
INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 98 (02): : 107 - 120
[34] 1,2-BIS(DIPHENYLPHOSPHINO)ETHANE BRIDGED DINUCLEAR COPPER(I) COMPLEXES - INVESTIGATIONS OF SOLID-STATE AND SOLUTION STRUCTURES BY CP/MAS P-31 NMR-SPECTROSCOPY, X-RAY CRYSTALLOGRAPHY, IR SPECTROSCOPY AND SOLUTION P-31 NMR AND CU-63 NMR-SPECTROSCOPY
VIJAYASHREE, N
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NETHAJI, M
CURRENT SCIENCE, 1993, 65 (01): : 57 - 67
[35] Synthesis and crystal structure of a cyanido bridged copper(II)-silver( I) bimetallic complex containing a trimeric {[Ag(CN)2]-}3 anion, [Cu(Dach)2-Ag(CN)2-Cu(Dach)2][Ag(CN)2]3 (Dach = cis-1,2-diaminocyclohexane)
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ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2017, 72 (01): : 43 - 47
[36] GROUP-11 METAL-IONS IN POLY(DONOR ATOM) ENVIRONMENTS - X-RAY CRYSTAL AND MOLECULAR-STRUCTURE OF [M((R,S)-1,2-(5-R-THIO-2-CH=N)2-C-HX)2](O3SCF3) (M=AG(I), R = ME, THIO = THIOPHENE, C-HX = CYCLOHEXANE) AND SILVER(I) AND COPPER(I) COORDINATION PROPERTIES IN SOLUTION (H-1, AG-109, AND N-15 NMR)-
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INORGANIC CHEMISTRY, 1985, 24 (09) : 1367 - 1375
[37] Mononuclear and mixed-metal copper(I)—silver(I) complexes containing 2,2′-bibenzimidazole and triphenylphosphane as ligands: crystal structures of [Cu(tmbbimH2)(PPh3)2](MeCOO)·0.2C7H8 and [Ag0.55Cu1.45(μ-bbim)(PPh3)4]·4CH2Cl2
Sebastião S. Lemos
Victor M. Deflon
Karl E. Bessler
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Transition Metal Chemistry, 2004, 29 : 46 - 50
[38] Mononuclear and mixed-metal copper(I)-silver(I) complexes containing 2,2′-bibenzimidazole and triphenylphosphane as ligands:: crystal structures of [Cu(tmbbimH2)(PPh3)2](MeCOO) • 0.2C7H8 and [Ag0.55Cu1.45(μ-bbim)(PPh3)4] • 4CH2Cl2
Lemos, SS
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Niquet, E
TRANSITION METAL CHEMISTRY, 2004, 29 (01) : 46 - 50
[39] PREFERENTIAL SOLVATION OF IONS IN MIXED-SOLVENTS .6. PREFERENTIAL SOLVATION OF LI+, NA+, K+, CU+, AG+, CL-, BR-, I-, NO3- AND CLO4- IONS IN ACETONITRILE + METHANOL MIXTURES USING VISCOSITY MEASUREMENTS
GILL, DS
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ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE NEUE FOLGE, 1984, 140 (02): : 149 - 156
[40] PREFERENTIAL SOLVATION OF IONS IN MIXED-SOLVENTS .5. PREFERENTIAL SOLVATION OF LI+, NA+, K+, CU+, AG+, CL-, BR-, I-, NO3- AND CLO4- IONS IN ACETONITRILE + METHANOL MIXTURES USING CONDUCTANCE MEASUREMENTS
GILL, DS
CHAUHAN, MS
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE NEUE FOLGE, 1984, 140 (02): : 139 - 148

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