CU-63 AND AG-109 NMR-STUDIES OF COPPER(I) AND SILVER(I) SALTS IN MIXED-SOLVENTS CONTAINING NITRILES

被引：36

作者：

GILL, DS ^{[1
]}

RODEHUSER, L ^{[1
]}

RUBINI, P ^{[1
]}

DELPUECH, JJ ^{[1
]}

机构：

[1] UNIV NANCY 1,ETUDES SYST ORGAN & COLLOIDAUX LAB,CNRS,URA 406,F-54506 VANDOEUVRE NANCY,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1995年 / 91卷 / 15期

关键词：

D O I：

10.1039/ft9959102307

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The solvation of copper(I) in mixed solvent systems containing acetonitrile or benzonitrile and the co-solvents propionitrile, butyronitrile, valeronitrile, as well as trimethyl-, triethyl- and tributyl-phosphite has been examined by Cu-63 NMR and also, in the case of the phosphites, by P-31 NMR. The concentration dependence and the variation of the chemical shift of the silver-109 signal with solvent composition have been studied in solutions of silver trifluoroacetate (AgO2CCF3).

引用

页码：2307 / 2312

页数：6

共 45 条

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