AN EXTENDED STUDY ON THE AVERAGE MOLECULAR-WEIGHTS OF NONLINEAR POLYMERS

被引：10
|
作者：
SHIAU, LD
机构：
[1] Department of Chemical Engineering, Chang Gung College of Medicine and Technology, Kweishan, Taoyuan
来源：
MACROMOLECULES | 1995年 / 28卷 / 18期
关键词：
D O I：
10.1021/ma00122a039
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A method is presented, based on the probability model proposed by Macosko and Miller, to calculate all the average molecular weights of nonlinear polymers. ($) over bar M(W), ($) over bar M(z), ($) over bar M(z+1), and higher average molecular weights can be determined as a function of reaction extent directly without the calculation of the whole distribution. The results indicate that this approach can be easily formulated and applied for many nonlinear polymerization reactions.
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页码：6273 / 6277
页数：5
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