LIGAND ENDOR STUDY OF THE TRIGONAL BIPYRAMIDAL COPPER-COMPLEXES, [CU(TREN)NH3](CLO4)(2) AND [CU(TREN)NCS]SCN IN THE POWDER STATE (TREN=TRIS(2-AMINOETHYL)AMINE)

被引：3

作者：

EHSAN, MQ ^{[1
]}

OHBA, Y ^{[1
]}

YAMAUCHI, S ^{[1
]}

IWAIZUMI, M ^{[1
]}

机构：

[1] TOHOKU UNIV, INST CHEM REACT SCI, SENDAI, MIYAGI 980, JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 02期

关键词：

D O I：

10.1246/cl.1995.151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The HFC and NQC constants for all the coordinating atoms of the ligand tren, tris(2-aminoethyl)amine, in the trigonal bipyramidal (tbp) copper complexes [Cu(tren)NH3](ClO4)(2) 1 and [Cu(tren)NCS]SCN 2 have been determined from the angle selected ENDOR study in the powder state. The spin distribution and the metal ligand bonding nature in the copper (tbp) complexes are discussed.

引用

页码：151 / 152

页数：2

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