SM(HESEO3)(SEO3).2H2O

被引:17
|
作者
KOSKENLINNA, M
MUTIKAINEN, I
LESKELA, M
NIINISTO, L
机构
[1] UNIV HELSINKI,DEPT CHEM,INORGAN CHEM LAB,SF-00014 HELSINKI,FINLAND
[2] HELSINKI UNIV TECHNOL,INORGAN & ANALYT CHEM LAB,SF-02150 ESPOO,FINLAND
关键词
D O I
10.1107/S0108270194002428
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structure of samarium hydrogenselenite selenite dihydrate is characterized by layers parallel to the xy plane consisting of SmO8 polyhedra linked by selenite and hydrogenselenite ions. A selenite ion links one Sm atom to three other Sm atoms while the hydrogenselenite ion acts as a monodentate bridging ligand to two Sm atoms. The layers are held together by hydrogen bonds and van der Waals forces. The coordination polyhedron of Sm is a distorted square antiprism.
引用
收藏
页码:1384 / 1386
页数:3
相关论文
共 50 条
  • [41] New copper selenites.: Part B:: Cu2(SeO3)2•H2O and Tl(III)2Cu3(SeO3)6
    Giester, G
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1999, 214 (05): : 305 - 308
  • [42] ELASTIC NONLINEARITY OF KH3(SEO3)2 AND KD3(SEO3)2 CRYSTALS
    SORGE, G
    BEIGE, H
    ALMEIDA, A
    SHUVALOV, LA
    PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1982, 73 (01): : K63 - K65
  • [43] Synthesis and crystal structure of Na3(H3O)[UO2(SeO3)2]2· H2O
    L. B. Serezhkina
    A. V. Vologzhanina
    A. V. Marukhnov
    D. V. Pushkin
    V. N. Serezhkin
    Crystallography Reports, 2009, 54 : 852 - 857
  • [44] Syntheses and crystal structures of the new compounds BaFe2(SeO3)4, AgFe(SeO3)2 and RbFe(SeO4)(SeO3)
    Giester, G
    JOURNAL OF ALLOYS AND COMPOUNDS, 2000, 308 (308) : 71 - 76
  • [45] THERMAL-EXPANSION AND SPONTANEOUS DEFORMATION OF KH3(SEO3)2,KD3(SEO3)2,K(H0,2D0,8)3(SEO3)2 FERROELASTICS
    IVANOV, NR
    IZVESTIYA AKADEMII NAUK SSSR SERIYA FIZICHESKAYA, 1979, 43 (08): : 1706 - 1712
  • [46] Nd2(SeO3)2(SeO4)•2H2O -: a mixed-valence compound containing selenium in the oxidation states +IV and +VI
    Berdonosov, PS
    Schmidt, P
    Dityat'yev, OA
    Dolgikh, VA
    Lightfoot, P
    Ruck, M
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2004, 630 (10): : 1395 - 1400
  • [47] Synthesis and Crystal Structure of Na3(H3O)[UO2(SeO3)2]2 • H2O
    Serezhkina, L. B.
    Vologzhanina, A. V.
    Marukhnov, A. V.
    Pushkin, D. V.
    Serezhkin, N.
    CRYSTALLOGRAPHY REPORTS, 2009, 54 (05) : 852 - 857
  • [48] Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)3
    Bang, Seong-eun
    Ok, Kang Min
    INORGANIC CHEMISTRY, 2015, 54 (17) : 8832 - 8839
  • [49] Thermal behavior of ferric selenite hydrates (Fe2(SeO3)3*3H2O, Fe2(SeO3)3*5H2O) and the water content in the natural ferric selenite mandarinoite
    Holzheid, Astrid
    Charykova, Marina V.
    Krivovichev, Vladimir G.
    Ledwig, Brendan
    Fokina, Elena L.
    Poroshina, Ksenia L.
    Platonova, Natalia V.
    Gurzhiy, Vladislav V.
    CHEMIE DER ERDE-GEOCHEMISTRY, 2018, 78 (02) : 228 - 240
  • [50] Syntheses and crystal structures of Pb(SeO3)2 and two modifications of Sn(SeO3)2
    Steinhauser, Georg
    Luef, Christoph
    Wildner, Manfred
    Giester, Gerald
    JOURNAL OF ALLOYS AND COMPOUNDS, 2006, 419 (1-2) : 45 - 49