ION-TRANSPORT IN GEL ELECTROLYTES

被引：40
|
作者：
REICHE, A
STEURICH, T
SANDNER, B
LOBITZ, P
FLEISCHER, G
机构：
[1] UNIV GREIFSWALD,DEPT CHEM,D-17489 GREIFSWALD,GERMANY
[2] UNIV LEIPZIG,DEPT PHYS & GEOSCI,D-04103 LEIPZIG,GERMANY
来源：
ELECTROCHIMICA ACTA | 1995年 / 40卷 / 13-14期
关键词：
GEL ELECTROLYTE; LITHIUM ION CONDUCTOR; IONIC CONDUCTIVITY; CATIONIC TRANSFERENCE NUMBER; PFG-NMR;
D O I：
10.1016/0013-4686(95)00156-9
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Gel electrolyte films were prepared by a redox initiated copolymerization of oligo(ethylene glycol)(23) dimethacrylate and acrylonitrile in the presence of oligo(ethylene glycol)(11) dimethyl ether as a plasticizer and LiCF3SO3. The influence of the polar comonomer acrylonitrile on the conductivity and the cationic transference number was investigated. The materials show conductivities between 10(-4) and 10(-5) S cm and transference numbers in the range of 0.5 at room temperature. Pulsed field gradient-NMR (PFG-NMR) measurements were carried out to determine the diffusion coefficients of the plasticizer by(1)H-NMR and of LiCF3SO3 by F-19-NMR.
引用
收藏
页码：2153 / 2157
页数：5
相关论文
共 50 条
  • [21] ENTEROTOXINS AND ION-TRANSPORT
    RAO, MC
    FIELD, M
    BIOCHEMICAL SOCIETY TRANSACTIONS, 1984, 12 (02) : 177 - 180
  • [22] ION-TRANSPORT ANTIBIOTICS
    DOBLER, M
    ACTA CRYSTALLOGRAPHICA SECTION A, 1984, 40 : C56 - C56
  • [23] ION-TRANSPORT IN CORNEA
    ZADUNAIS.JA
    AMERICAN JOURNAL OF OPHTHALMOLOGY, 1973, 76 (06) : 1018 - 1018
  • [24] ION-TRANSPORT BY THE CORNEA
    WIEDERHOLT, M
    NEWS IN PHYSIOLOGICAL SCIENCES, 1988, 3 : 97 - 99
  • [25] ION-TRANSPORT IN YEAST
    BORSTPAUWELS, GWFH
    BIOCHIMICA ET BIOPHYSICA ACTA, 1981, 650 (2-3) : 88 - 127
  • [26] ION-TRANSPORT IN SSFLCDS
    MAXIMUS, B
    DELEY, E
    DEMEYERE, A
    PAUWELS, H
    FERROELECTRICS, 1991, 121 (1-4) : 103 - 112
  • [27] REGULATION OF ION-TRANSPORT
    GLASS, ADM
    ANNUAL REVIEW OF PLANT PHYSIOLOGY AND PLANT MOLECULAR BIOLOGY, 1983, 34 : 311 - 326
  • [28] Ion transport properties of ionic liquid based gel electrolytes
    Sekhon, S. S.
    Kaur, D. P.
    Park, J. -S.
    Yamada, K.
    ELECTROCHIMICA ACTA, 2012, 60 : 366 - 374
  • [29] Lithium ion transport in polymer, gel and composite electrolytes.
    Londergan, CH
    Han, AY
    Dai, HL
    Davey, JR
    Zawodzinski, TA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 217 : U500 - U500
  • [30] Ion Transport in Solvated Sodium-Ion Conducting Gel Polymer Electrolytes
    Kuray, Preeya
    Mei, Wenwen
    Sheffield, Sarah E.
    Sengeh, Joseph
    Pulido, Carlos Rolando Fernandez
    Capparelli, Clara
    Hickey, Robert J.
    Hickner, Michael A.
    FRONTIERS IN ENERGY RESEARCH, 2020, 8
12345