THE 1ST LITHIUM PHENOLATE WITH A TRINUCLEAR STRUCTURE AND THE TETRANUCLEAR PRODUCT OF 1/1 ADDITION OF LITHIUM IODIDE - X-RAY STRUCTURES OF [LIOAR]3 AND [LI2(OAR)I]2 [OAR = OC6H2(CH2NME2)2-2,6-ME-4]

被引：50
|
作者：
VANDERSCHAAF, PA
HOGERHEIDE, MP
GROVE, DM
SPEK, AL
VANKOTEN, G
机构：
[1] UNIV UTRECHT,DEPT MET MEDIATED SYNTH,DEBYE RES INST,PADUALAAN 8,3584 CH UTRECHT,NETHERLANDS
[2] UNIV UTRECHT,CRYSTAL & STRUCT CHEM LAB,BIJVOET CTR BIOMOLEC RES,3584 CH UTRECHT,NETHERLANDS
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 23期
关键词：
D O I：
10.1039/c39920001703
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of 2,6-bis[(dimethylamino)methyl]-4-methylphenol with n-butyllithium affords quantitatively [LiOAr]3 [OAr = OC6H2(CH2NMe2)2-2,6-Me-4] 1, which has an unprecedented trinuclear structure both in solution (cryoscopy in C6H6) and in the solid state (X-ray); 1 reacts selectively with Lil to form the adduct [Li2(OAr)l]2 2 which has a tetranuclear structure (X-ray).
引用
收藏
页码：1703 / 1705
页数：3
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