HIGH-TEMPERATURE AND HIGH-RESOLUTION UV PHOTOELECTRON-SPECTROSCOPY USING SUPERSONIC MOLECULAR-BEAMS

被引：11
|
作者：
WANG, LS [1 ]
REUTTROBEY, JE [1 ]
NIU, B [1 ]
LEE, YT [1 ]
SHIRLEY, DA [1 ]
机构：
[1] UNIV MARYLAND,DEPT CHEM,COLLEGE PK,MD 20742
来源：
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 1990年 / 51卷
关键词：
D O I：
10.1016/0368-2048(90)80177-C
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
A high temperature molecular beam source with electron bombardment heating has been built for high resolution photoelectron spectroscopic studies of high temperature species and clusters. This source has the advantages of: (1) producing an intense, continuous, seeded molecular beam, (2) eliminating the interference of the heating mechanism from the photoelectron measurement. Coupling the source with our hemispherical electron energy analyzer, we can obtain very high resolution HeIα (584Å) photoelectron spectra of high temperature species. Vibrationally-resolved photoelectron spectra of PbSe, As2, As4, and ZnCl2 are shown to demonstrate the performance of the new source. © 1990.
引用
收藏
页码：513 / 526
页数：14
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