SPIN-SELECTIVE RECOMBINATION IN GEMINATE RADICAL PAIRS INVOLVING ELECTRONICALLY EXCITED RADICALS STUDIED BY MFE AND CIDEP

被引：5
|
作者：
BATCHELOR, SN
MCLAUCHLAN, KA
SHKROB, IA
机构：
[1] UNIV OXFORD,PHYS CHEM LAB,S PARKS RD,OXFORD OX1 3QZ,ENGLAND
[2] ARGONNE NATL LAB,DIV CHEM,ARGONNE,IL 60439
来源：
CHEMICAL PHYSICS LETTERS | 1993年 / 214卷 / 05期
关键词：
D O I：
10.1016/0009-2614(93)85674-D
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Magnetic field effects are reported from radical combination reactions involving electronically excited diphenylmethyl and para-substituted benzyl radicals created, along with a ground-state radical, by laser flash photolysis of micellized ketones. A parallel CIDEP study of ground-state radicals displayed inverse behaviour. The results are thought to shed light on the diffusional processes occurring in micellar solutions.
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页码：507 / 512
页数：6
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