SPIN-SELECTIVE RECOMBINATION IN GEMINATE RADICAL PAIRS INVOLVING ELECTRONICALLY EXCITED RADICALS STUDIED BY MFE AND CIDEP

被引：5
|
作者：
BATCHELOR, SN
MCLAUCHLAN, KA
SHKROB, IA
机构：
[1] UNIV OXFORD,PHYS CHEM LAB,S PARKS RD,OXFORD OX1 3QZ,ENGLAND
[2] ARGONNE NATL LAB,DIV CHEM,ARGONNE,IL 60439
来源：
CHEMICAL PHYSICS LETTERS | 1993年 / 214卷 / 05期
关键词：
D O I：
10.1016/0009-2614(93)85674-D
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Magnetic field effects are reported from radical combination reactions involving electronically excited diphenylmethyl and para-substituted benzyl radicals created, along with a ground-state radical, by laser flash photolysis of micellized ketones. A parallel CIDEP study of ground-state radicals displayed inverse behaviour. The results are thought to shed light on the diffusional processes occurring in micellar solutions.
引用
收藏
页码：507 / 512
页数：6
相关论文
共 30 条
  • [1] Production of electronically excited states by geminate recombination of radicals.
    Mendenhall, GD
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 217 : U352 - U352
  • [2] Evolution of spin coherence of radical pairs due to spin-selective recombination: Comparison of three models
    Bagryansky, Victor A.
    Chetverikov, Artem O.
    Borovkov, Vsevolod I.
    Molin, Yuri N.
    JOURNAL OF CHEMICAL PHYSICS, 2023, 159 (24):
  • [3] THE INFLUENCE OF COULOMB AND EXCHANGE INTERACTIONS AND OF REACTIVITY ON RECOMBINATION KINETICS AND CIDEP OF GEMINATE RADICAL PAIRS
    KRISSINEL, EB
    SHOKHIREV, NV
    CHEMICAL PHYSICS, 1990, 143 (01) : 67 - 74
  • [4] Spin-selective recombination reactions of radical pairs: Experimental test of validity of reaction operators
    Maeda, Kiminori
    Liddell, Paul
    Gust, Devens
    Hore, P. J.
    JOURNAL OF CHEMICAL PHYSICS, 2013, 139 (23):
  • [5] Comment on a shape of EPR spectra of spin-correlated radical pairs and separate radicals escaped geminate recombination
    K. M. Salikhov
    Applied Magnetic Resonance, 1997, 13 : 415 - 437
  • [6] Comment on a shape of EPR spectra of spin-correlated radical pairs and separate radicals escaped geminate recombination
    Salikhov, KM
    APPLIED MAGNETIC RESONANCE, 1997, 13 (3-4) : 415 - 437
  • [7] Spin-selective reactions of radical pairs act as quantum measurements
    Jones, J. A.
    Hore, P. J.
    CHEMICAL PHYSICS LETTERS, 2010, 488 (1-3) : 90 - 93
  • [8] Spin-Selective Reaction with a Third Radical Destroys Spin Correlation in the Surviving Radical Pairs
    Borovkov, Vsevolod I.
    Ivanishko, Irina S.
    Bagryansky, Victor A.
    Molin, Yuri N.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 117 (08): : 1692 - 1696
  • [9] On the verification of different approaches describing spin-selective radical recombination
    Bagryansky, V. A.
    Borovkov, V. I.
    Molin, Yu N.
    CHEMICAL PHYSICS LETTERS, 2013, 570 : 141 - 146
  • [10] Reaction operators for spin-selective chemical reactions of radical pairs
    Jones, J. A.
    Maeda, Kiminori
    Hore, P. J.
    CHEMICAL PHYSICS LETTERS, 2011, 507 (4-6) : 269 - 273
123