CRYSTAL-STRUCTURE OF CIS-(CARBON MONOXIDE)(ETA-1-CARBON DIOXIDE)BIS(2,2'-BIPYRIDYL)RUTHENIUM, AN ACTIVE SPECIES IN CATALYTIC CO2 REDUCTION AFFORDING CO AND HCOO-

被引：74

作者：

TANAKA, H ^{[1
]}

NAGAO, H ^{[1
]}

PENG, SM ^{[1
]}

TANAKA, K ^{[1
]}

机构：

[1] GRAD UNIV ADV STUDIES,INST MOLEC SCI,DEPT STRUCT MOLEC SCI,MYODAIJI,OKAZAKI 444,JAPAN

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 04期

关键词：

D O I：

10.1021/om00040a010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A reaction of [Ru(bpy)2(CO)2](PF6)2 with 2 equiv of Bu4NOH in H2O/EtOH (1:1 v/v) affords an eta(1)-CO2 complex, [Ru(bpy)2(CO)(COO)].3H2O. An addition of an aqueous HCl solution to a MeOH solution of [Ru(bpy)2-(CO)(COO)].3H2O quantitatively regenerates [Ru(bpy)2-(CO)2]2+.

引用

页码：1450 / 1451

页数：2

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