THE [NI(CO)4]-PROMOTED CARBONYLATIVE CYCLOADDITION OF ALKYNES AND ALLYL HALIDES FOR THE SYNTHESIS OF 2-CYCLOPENTENONE DERIVATIVES

被引：18
|
作者：
LLEBARIA, A [1 ]
MORETO, JM [1 ]
机构：
[1] CSIC,CID,DEPT QUIM ORGAN BIOL,JORDI GIRONA 18-26,E-08034 BARCELONA,SPAIN
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 451卷 / 1-2期
关键词：
D O I：
10.1016/0022-328X(93)83002-D
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The [Ni(CO)4]-mediated carbonylative cycloaddition of alkynes and allyl halides first reported by Chiusoli, has been reviewed, extended and optimized for application to cyclopentenone synthesis. An insight into the reaction mechanism is also given to explain the results obtained, in particular the regio- and stereo-chemistry of the process.
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页码：1 / 13
页数：13
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