AN EFFICIENT PROCEDURE FOR THE SYNTHESIS OF C-CHIRAL BISPHOSPHINES

被引：97
|
作者：
MCKINSTRY, L [1 ]
LIVINGHOUSE, T [1 ]
机构：
[1] MONTANA STATE UNIV,DEPT CHEM & BIOCHEM,BOZEMAN,MT 59717
来源：
TETRAHEDRON | 1995年 / 51卷 / 28期
关键词：
D O I：
10.1016/0040-4020(95)00390-T
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A practical method for the synthesis of bisphosphines containing homochiral carbon backbones is described. This procedure entails sequential reaction of a homochiral ditosylate with the appropriate dialkyl- or diarylphosphine-borane anion followed by BH5 decomplexation mediated by HBF4 . OMe(2).
引用
收藏
页码：7655 / 7666
页数：12
相关论文
共 50 条
  • [21] Asymmetric synthesis of homoproline derivatives via Rh(I)catalyzed hydrogenation using chiral bisphosphines as ligands
    Zhang, YH
    Park, JH
    Lee, SG
    TETRAHEDRON-ASYMMETRY, 2004, 15 (14) : 2209 - 2212
  • [22] Metal-free metathesis reaction of C-chiral allylic sulfilimines with aryl isocyanates: Construction of chiral nonracemic allylic isocyanates
    Evans, P. Andrew, 1600, American Chemical Society (136):
  • [23] Metal-free metathesis reaction of C-chiral allylic sulfilimines with aryl isocyanates: Construction of chiral nonracemic allylic isocyanates
    Grange, Rebecca
    Evans, P. Andrew
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
  • [24] Efficient synthesis of chiral C2-substituted norbornene derivatives
    Ye, Jinxiang
    Qi, Lifang
    Cheng, Hong-Gang
    Zhou, Qianghui
    CHINESE SCIENCE BULLETIN-CHINESE, 2025, 70 (10): : 1440 - 1445
  • [25] Efficient chiral pool synthesis of the C1-C6 fragment of epothilones
    Klar, U
    Röhr, B
    Kuczynski, F
    Schwede, W
    Berger, M
    Skuballa, W
    Buchmann, B
    SYNTHESIS-STUTTGART, 2005, (02): : 301 - 305
  • [26] Copper(Ⅰ)-catalyzed diastereodivergent construction of vicinal P-chiral and C-chiral centers facilitated by dual “soft-soft” interaction
    Yan-Bo Li
    Yi Li
    Liang Yin
    Chinese Chemical Letters, 2024, 35 (07) : 290 - 296
  • [27] FERROELECTRICITY IN LIQUID-CRYSTALS - C-CHIRAL SMECTIC MESOPHASE - MOLECULAR STRUCTURE-PROPERTY RELATIONS
    DECOBERT, G
    DUBOIS, JC
    NOUVEAU JOURNAL DE CHIMIE-NEW JOURNAL OF CHEMISTRY, 1986, 10 (12): : 777 - 782
  • [28] AN EFFICIENT CHIRAL SYNTHESIS OF (+)-SESBANINE
    TOMIOKA, K
    KOGA, K
    TETRAHEDRON LETTERS, 1980, 21 (24) : 2321 - 2324
  • [29] Copper(I)-catalyzed diastereodivergent construction of vicinal P-chiral and C-chiral centers facilitated by dual "soft-soft" interaction
    Li, Yan-Bo
    Li, Yi
    Yin, Liang
    CHINESE CHEMICAL LETTERS, 2024, 35 (07)
  • [30] Synthesis of C2-Symmetric Bisphosphines and Their Application in Enantioselective Transition Metal Catalysis
    Gok, Halil Zeki
    Kilicarslan, Seda
    Gok, Yasar
    CROATICA CHEMICA ACTA, 2018, 91 (01) : 89 - 97
12345