AN EFFICIENT PROCEDURE FOR THE SYNTHESIS OF C-CHIRAL BISPHOSPHINES

被引：97

作者：

MCKINSTRY, L ^{[1
]}

LIVINGHOUSE, T ^{[1
]}

机构：

[1] MONTANA STATE UNIV,DEPT CHEM & BIOCHEM,BOZEMAN,MT 59717

来源：

TETRAHEDRON | 1995年 / 51卷 / 28期

关键词：

D O I：

10.1016/0040-4020(95)00390-T

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A practical method for the synthesis of bisphosphines containing homochiral carbon backbones is described. This procedure entails sequential reaction of a homochiral ditosylate with the appropriate dialkyl- or diarylphosphine-borane anion followed by BH5 decomplexation mediated by HBF4 . OMe(2).

引用

页码：7655 / 7666

页数：12

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