ON THE REACTION OF THE HALOGENES CL2, BR2 AND I2 WITH CH3OSO+MF6-(M = AS, SB)

被引：0
|
作者：
MINKWITZ, R
GERHARD, V
机构：
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1991年 / 46卷 / 11期
关键词：
PREPARATION; IR SPECTRA; NMR SPECTRA;
D O I：
10.1515/znb-1991-1104
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Chlorine reacts with CH3OSO+MF6- (M = As, Sb) at 298 K to form AsCl4+AsF6- and SbCl4+Sb2Cl2F9-, respectively. The analogous reactions with bromine at 233 K result in the formation of (CH3)2Br+AsF6- and Sb2F11-. With iodine, the new methyliodonium salts (CH3I2)n(n+)(MF6-)n(M = As, Sb) with yet unknown constitution are obtained.
引用
收藏
页码：1470 / 1472
页数：3
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