ON THE REACTION OF THE HALOGENES CL2, BR2 AND I2 WITH CH3OSO+MF6-(M = AS, SB)

被引：0
|
作者：
MINKWITZ, R
GERHARD, V
机构：
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1991年 / 46卷 / 11期
关键词：
PREPARATION; IR SPECTRA; NMR SPECTRA;
D O I：
10.1515/znb-1991-1104
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Chlorine reacts with CH3OSO+MF6- (M = As, Sb) at 298 K to form AsCl4+AsF6- and SbCl4+Sb2Cl2F9-, respectively. The analogous reactions with bromine at 233 K result in the formation of (CH3)2Br+AsF6- and Sb2F11-. With iodine, the new methyliodonium salts (CH3I2)n(n+)(MF6-)n(M = As, Sb) with yet unknown constitution are obtained.
引用
收藏
页码：1470 / 1472
页数：3
相关论文
共 50 条
  • [1] IONIZING COLLISIONS OF CESIUM WITH CL2, BR2, AND I2
    TANG, SY
    LEFFERT, CB
    ROTHE, EW
    RECK, GP
    JOURNAL OF CHEMICAL PHYSICS, 1975, 62 (01): : 132 - 135
  • [2] Observations of Cl2, Br2, and I2 in coastal marine air
    Finley, B. D.
    Saltzman, E. S.
    JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2008, 113 (D21)
  • [3] MODEL POTENTIAL SCF CALCULATIONS ON CL2, BR2, AND I2
    GROPEN, O
    HUZINAGA, S
    MCLEAN, AD
    JOURNAL OF CHEMICAL PHYSICS, 1980, 73 (01): : 402 - 406
  • [4] Theoretical study on the nonadiabatic transitions in the photodissociation of Cl2, Br2, and I2
    Asano, Y
    Yabushita, S
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2003, 24 (06) : 703 - 711
  • [5] Rate coefficients for the reaction of OH with Cl2, Br2, and I2 from 235 to 354 K
    Gilles, MK
    Burkholder, JB
    Ravishankara, AR
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1999, 31 (06) : 417 - 424
  • [6] THE ELECTRICAL PROPERTIES OF POLYCRYSTALLINE SELENIUM WITH HALOGEN IMPURITIES (BR2, CL2, I2)
    GEIKHMAN, DS
    ROMANKEVICH, VN
    SIDYAKIN, VG
    SOVIET PHYSICS-SOLID STATE, 1959, 1 (02): : 196 - 202
  • [7] INFRARED ABSORBTION OF LIQUID BR2,I2, AND BR2 - I2
    WAGNER, V
    ZEITSCHRIFT FUR PHYSIK, 1969, 224 (04): : 353 - &
  • [8] Quenching reactions of NF(a1Δ) by Cl2, ClF, Br2, ICI, IF, and I2
    Du, Kang Yan
    Setser, D.W.
    Journal of Physical Chemistry, 1992, 96 (06):
  • [9] SOLID-STATE EFFECTS IN THE MOLECULAR-CRYSTALS OF CL2, BR2 AND I2
    BLAHA, P
    SCHWARZ, K
    JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 1992, 93 : 355 - 365
  • [10] ADIABATIC ELECTRON AFFINITIES OF CL2, BR2, I2, IBR, NO2 AND O2
    BAEDE, APM
    PHYSICA, 1972, 59 (03): : 541 - +
12345