SYNTHESIS, STRUCTURE AND MAGNETIC-PROPERTIES OF A LINEAR TRIMANGANESE(III,II,III) COMPLEX BRIDGED WITH A (MU-HYDROXO)BIS(MU-ACETATO) UNIT

被引：38

作者：

KITAJIMA, N

OSAWA, M

IMAI, S

FUJISAWA, K

MOROOKA, Y

HEERWEGH, K

REED, CA

BOYD, PDW

机构：

[1] UNIV SO CALIF, DEPT CHEM, LOS ANGELES, CA 90089 USA

[2] UNIV AUCKLAND, DEPT CHEM, AUCKLAND, NEW ZEALAND

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 21期

关键词：

D O I：

10.1021/ic00099a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A trinuclear mixed-valence trimanganese(III,II,III) complex [Mn(HB(3,5-iPr(2)pz)(3))]-(OH)(OAc)(2)Mn(OH)(OAc)(2)[Mn(HB(3,5-iPr(2)pz)(3))] was obtained by treatment of the (mu-hydroxo)(mu-acetato)dimanganese(II,II) dimer with excess H2O2. The trimeric Linear structure bridged with a (mu-hydroxo)bis(mu-acetato) group was revealed by X-ray crystallography. The structural features are consistent with the valence assignment. The valiable temperature magnetic susceptibility indicates that the cluster is weakly antiferromagnetically coupled through the (mu-hydroxo)bis(mu-acetato) bridge.

引用

页码：4613 / 4614

页数：2

共 50 条

[41] STRUCTURE AND PROPERTIES OF A DIMERIC HYDROXO-BRIDGED YTTERBIUM(III) COMPLEX, DI-MU-HYDROXO-BIS[TRIAQUO(PYRIDINE-2-CARBOXALDEHYDE "2'-PYRIDYLHYDRAZONE)YTTERBIUM(III)] TETRACHLORIDE TETRAHYDRATE
BARANIAK, E
BRUCE, RSL
FREEMAN, HC
HAIR, NJ
JAMES, J
[J]. INORGANIC CHEMISTRY, 1976, 15 (09) : 2226 - 2230
[42] SYNTHESIS AND PROPERTIES OF TRI-MU-HYDROXO-BIS[TRIS(PYRIDINE)COBALT(III)PERCHLORATE
LAIER, T
SPRINGBORG, J
[J]. ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1981, 35 (02): : 145 - 146
[43] Synthesis, Structure, and Magnetic Properties of a Mononuclear Chiral (Acetato)bis(aminoalkoxido) manganese(III) Complex
Kornowicz, Arkadiusz
Terlecki, Michal
Prochowicz, Daniel
Pichon, Celine
Justyniak, Iwona
Bury, Wojciech
Wrobel, Zbigniew
Sutter, Jean-Pascal
Lewinski, Janusz
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (10) : 1392 - 1395
[44] Synthesis, X-ray structure, and magnetic properties of ferromagnetically coupled binuclear copper(I) complexes having a (mu-hydroxo/methoxo)bis(mu-benzoato)dicopper(II) core
Geetha, K
Nethaji, M
Chakravarty, AR
Vasanthacharya, NY
[J]. INORGANIC CHEMISTRY, 1996, 35 (26) : 7666 - 7670
[45] NEW TRIPLY HYDROXO-BRIDGED COMPLEXES OF CHROMIUM(III), COBALT(III), AND RHODIUM(III) - CRYSTAL-STRUCTURE OF TRIS(MU-HYDROXO)BIS[(1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE)CHROMIUM(III)] TRIIODIDE TRIHYDRATE
WIEGHARDT, K
CHAUDHURI, P
NUBER, B
WEISS, J
[J]. INORGANIC CHEMISTRY, 1982, 21 (08) : 3086 - 3090
[46] REVERSIBLE PROTONATION OF THE OXO BRIDGE IN A HEMERYTHRIN MODEL-COMPOUND - SYNTHESIS, STRUCTURE, AND PROPERTIES OF (MU-HYDROXO)BIS(MU-ACETATO)BIS[HYDROTRIS(1-PYRAZOLYL)BORATO]DIIRON(III), [(HB(PZ)3)FE(OH)(O2CCH3)2FE(HB(PZ)3)]+
ARMSTRONG, WH
LIPPARD, SJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (16) : 4632 - 4633
[47] Synthesis and structure of a dimeric hydroxo-bridged erbium(III) complex, di-mu-hydroxo-bis[(1,4,7,10,13,16-hexaazacyclooctadecane)erbium(III)] tetra(trifloromethanesulfonate)
Wang, RY
Zhao, JJ
Jin, TZ
Xu, GX
Zhou, ZY
Zhou, XG
[J]. POLYHEDRON, 1998, 17 (01) : 43 - 47
[48] STRUCTURAL AND ELECTRONIC-PROPERTIES OF TETRANUCLEAR IRON(III) PYRIDYLAMINE COMPLEXES CONTAINING COFACIAL PAIRS OF MU-OXO-BIS(MU-ACETATO)IRON(III) MOIETIES - MODELS FOR MET HEMERYTHRINS
TOFTLUND, H
MURRAY, KS
ZWACK, PR
TAYLOR, LF
ANDERSON, OP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (03) : 191 - 193
[49] SYNTHESIS AND REACTIVITY OF HYDROXO-BRIDGED BINUCLEAR ETHYLENEDIAMINE COMPLEXES OF IRIDIUM(III) AND THE X-RAY CRYSTAL-STRUCTURE OF [AQUABIS(ETHYLENEDIAMINE)IRIDIUM(III)]-(MU-HYDROXO)HYDROXOBIS(ETHYLENEDIAMINE)IRIDIUM(III) DITHIONATE PERCHLORATE HYDRATE
GALSBOL, F
LARSEN, S
RASMUSSEN, B
SPRINGBORG, J
[J]. INORGANIC CHEMISTRY, 1986, 25 (03) : 290 - 297
[50] INTRAMOLECULAR ELECTRON-TRANSFER REACTIONS IN BRIDGED POLYNUCLEAR RUII-COIII COMPLEXES CONTAINING A (MU-CARBOXYLATO)BIS(MU-HYDROXO)BIS[(AMINE)COBALT(III)] (AND A RUII(NH3)5) STRUCTURAL UNIT
NEVES, A
HERRMANN, W
WIEGHARDT, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (19) : 5532 - 5537

← 1 2 3 4 5 →