ROSE BENGAL-INDUCED PHOTOFRAGMENTATION - SINGLET OXYGEN REVISITED

被引：2
|
作者：
EPLING, GA
JACKSON, ML
机构：
[1] Department of Chemistry, University of Connecticut, Storrs
来源：
TETRAHEDRON LETTERS | 1991年 / 32卷 / 51期
关键词：
SINGLET OXYGEN; ELECTRON TRANSFER; PHOTOFRAGMENTATION; AMINO ALCOHOL; PHOTOLYSIS;
D O I：
10.1016/0040-4039(91)80519-C
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The Rose Bengal-induced photofragmentation of beta-amino alcohols has been previously reported to proceed through a mechanism involving singlet oxygen sensitization, followed by attack of singlet oxygen and superoxide on the beta-amino alcohol. An alternative mechanism involving electron transfer from the amine to the excited state Rose Bengal is supported by new evidence.
引用
收藏
页码：7507 / 7510
页数：4
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