Catalytic Activation of C-C and C-H Bonds in Alkanes under Mild Conditions

被引：0
|
作者：
Akhmedov, V. M. [1 ]
机构：
[1] Azerbaijan Natl Acad Sci, Inst Chem Problems, AZ-1143 Baku, Azerbaijan
来源：
CATALYSIS IN INDUSTRY | 2014年 / 6卷 / 04期
关键词：
alkane activation; metal nanoparticles; vapor metal condensation; catalysts;
D O I：
10.1134/S2070050414040035
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Heterogeneous compositions capable of activating C-H and C-C bonds in alkanes under mild conditions have been obtained by reacting metal oxides with various morphologies with "metal solutions" prepared by metal vapor condensation. The physicochemical analysis carried out in this study suggests that the metal particles in these catalysts are mostly nanosized. The catalytic properties of the compositions have been investigated in the hydroreforming of C-5-C-16 n-alkanes. These compositions can be used to obtain promising catalysts for the structural conversion of n-alkanes into environmentally friendly high-octane gas-oline and lubricants.
引用
收藏
页码：253 / 259
页数：7
相关论文
共 50 条
  • [1] Catalytic activation of C-C and C-H bonds in alkanes under mild conditions
    V. M. Akhmedov
    [J]. Catalysis in Industry, 2014, 6 (4) : 253 - 259
  • [2] ACTIVATION OF C-H AND C-C BONDS IN ETHYLENE AND PIPERYLENE CATALYTIC REACTIONS
    BELOV, GP
    DZHABIEV, TS
    KOLESNIKOV, IM
    [J]. JOURNAL OF MOLECULAR CATALYSIS, 1982, 14 (01): : 105 - 112
  • [3] Formation of C-C bonds for the production of bio-alkanes under mild conditions
    Xin, Jiayu
    Zhang, Suojiang
    Yan, Dongxia
    Ayodele, Olubunmi
    Lu, Xingmei
    Wang, Jianji
    [J]. GREEN CHEMISTRY, 2014, 16 (07) : 3589 - 3595
  • [4] Pd-catalyzed selective addition of heteroaromatic C-H bonds to C-C triple bonds under mild conditions
    Lu, WJ
    Jia, CG
    Kitamura, T
    Fujiwara, Y
    [J]. ORGANIC LETTERS, 2000, 2 (19) : 2927 - 2930
  • [5] THEORETICAL-STUDIES OF THE ACTIVATION OF C-H AND C-C BONDS
    SCHULE, J
    [J]. JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 1988, 47 : 155 - 158
  • [6] Homogeneous catalytic oxidation of light alkanes: C-C bond cleavage under mild conditions
    E. G. Chepaikin
    A. P. Bezruchenko
    G. N. Menchikova
    N. I. Moiseeva
    A. E. Gekhman
    [J]. Kinetics and Catalysis, 2010, 51 : 666 - 671
  • [7] Homogeneous Catalytic Oxidation of Light Alkanes: C-C Bond Cleavage under Mild Conditions
    Chepaikin, E. G.
    Bezruchenko, A. P.
    Menchikova, G. N.
    Moiseeva, N. I.
    Gekhman, A. E.
    [J]. KINETICS AND CATALYSIS, 2010, 51 (05) : 666 - 671
  • [8] Efficient activation of aromatic C-H bonds for addition to C-C multiple bonds
    Jia, CG
    Piao, DG
    Oyamada, JZ
    Lu, WJ
    Kitamura, T
    Fujiwara, Y
    [J]. SCIENCE, 2000, 287 (5460) : 1992 - 1995
  • [9] Bimetallic nanosized solids with acid and redox properties for catalytic activation of C-C and C-H bonds
    Cabrero-Antonino, Jose R.
    Tejeda-Serrano, Maria
    Quesada, Manuel
    Vidal-Moya, Jose A.
    Leyva-Perez, Antonio
    Corma, Avelino
    [J]. CHEMICAL SCIENCE, 2017, 8 (01) : 689 - 696
  • [10] DIRECT CATALYTIC CLEAVAGE AND FUNCTIONALIZATION OF C-H AND C-C BONDS OF ALKANES, INCLUDING METHANE, USING DIOXYGEN AS OXIDANT
    LIN, MR
    SEN, AM
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 210 : 48 - INOR
12345