COPPER(I) HEXAFLUOROSILICATE PI-COMPLEXES WITH ALLYLAMMONIUM SALTS - SYNTHESIS AND CRYSTAL-STRUCTURE OF [CUOOCH.C3H5NH3]2SIF6 AND [CU2CL3.2C3H5NH3]2SIF6

被引：0

作者：

OLIJNIK, VV ^{[1
]}

GORESHNIK, EA ^{[1
]}

PECHARSKY, VK ^{[1
]}

BUDARIN, LI ^{[1
]}

MYSKIV, MG ^{[1
]}

机构：

[1] UKRAINIAN ACAD SCI,INST PHYS CHEM,KIEV,UKRAINE

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 1993年 / 34卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel copper (I) pi-complexes containing the SiF62- anion have been synthesized and studied by X-ray structure analysis. The crystals of the first title compound (A) are monoclinic, space group P2(1)/b with a = 13.039(5), b = 10.586(4), c = 6.072(2) angstrom, gamma = 100.23(2)-degrees, and Z = 2. The crystals of the second title compound (B) are triclinic, space group P1BAR with a = 14.495(5), b = 7.633(2), c = 6 429(8) angstrom, alpha = 90.67(8), beta = 81.80(8), gamma = 94.05(3)-degrees, and Z = 1. In structure A, the copper cations and the bridge formiate anions form infinite [Cu(HCOO)]n spirals, which are cross-linked due to the pi-interaction between copper and the double bond AA and the strong hydrogen bonds N-H...F(SiF62-) to form a three-dimensional framework. In structure B, allylammonium similarly acts as a bridge linking the SiF62- and Cu4Cl62- anions into layers.

引用

页码：615 / 621

页数：7

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