AN ELECTROANALYTICAL INVESTIGATION OF POLYBITHIOPHENE MODIFIED PLATINUM-ELECTRODES

被引：4
|
作者：
TORSI, L
DEGIGLIO, E
SABBATINI, L
ZAMBONIN, PG
机构：
[1] Laboratorio di Chimica Analitica, Dipartimento di Chimica dell'Universita’ di Bari
来源：
JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1994年 / 141卷 / 10期
关键词：
D O I：
10.1149/1.2059132
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
An electroanalytical investigation of the polybithiophene (PBT) band structure has been performed through the study of the voltammetric response of redox systems like ferrocene (FeC(p)2) and p-benzoquinone (p-BQ) at Pt/PBT working electrode. The FeC(p)2 response suggests a semiconducting behavior of the PBT polymer and the p-BQ voltammetric response can be used to indirectly test modifications of the polymer band structure occurring when the polymer is overoxidized; in particular the presence of states in the middle of the bandgap can be inferred.
引用
收藏
页码：2608 / 2610
页数：3
相关论文
共 50 条
  • [41] THE ELECTROOXIDATION OF GLUCOSE ON PLATINUM-ELECTRODES IN BUFFERED MEDIA
    DEMELE, MFL
    VIDELA, HA
    ARVIA, AJ
    BIOELECTROCHEMISTRY AND BIOENERGETICS, 1983, 10 (2-3): : 239 - 249
  • [42] ARSENIC CONTAMINATION AND POSSIBILITY OF REGENERATING PLATINUM-ELECTRODES
    SUTYAGINA, AA
    KUZNETSOVA, TI
    ILCHENKO, NI
    VOVCHENKO, GD
    SOVIET ELECTROCHEMISTRY, 1977, 13 (08): : 1025 - 1027
  • [43] CHARACTERIZATION OF PLATINUM-ELECTRODES BY INFRARED-SPECTROSCOPY
    BENZIGER, JB
    PASCAL, FA
    BERNASEK, SL
    SORIAGA, MP
    HUBBARD, AT
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 198 (01) : 65 - 80
  • [44] INSITU STM STUDIES OF POLYCRYSTALLINE PLATINUM-ELECTRODES
    SZKLARCZYK, M
    BOCKRIS, JO
    SURFACE SCIENCE, 1991, 241 (1-2) : 54 - 60
  • [45] ADSORPTION OF COPPER ADATOMS ON SMOOTH PLATINUM-ELECTRODES
    SAFONOV, VA
    LAPA, AS
    MANSUROV, GN
    PETRII, OA
    SOVIET ELECTROCHEMISTRY, 1980, 16 (03): : 375 - 379
  • [46] ELECTROREDUCTION OF ACIDIC NITROMETHANE SOLUTIONS ON PLATINUM-ELECTRODES
    TEIJELO, ML
    MACAGNO, VA
    GIORDANO, MC
    ANALES DE LA ASOCIACION QUIMICA ARGENTINA, 1978, 66 (06): : 333 - 344
  • [47] VOLTAMETRIC BEHAVIOR OF PLATINUM-ELECTRODES IN UNBUFFERED SOLUTIONS
    BORMANN, HD
    GEYER, R
    HUNDHAMM.B
    ZEITSCHRIFT FUR CHEMIE, 1973, 13 (04): : 148 - 149
  • [48] INVESTIGATION OF IMPEDANCE OF NICKEL AND PLATINUM-ELECTRODES IN A HYDRATED EQUIMOLAR KOH-NAOH MELT
    BUDNIK, VG
    ZARUBITSKII, OG
    JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1975, 48 (07): : 1694 - 1696
  • [49] CHEMICALLY MODIFIED ELECTRODES .20. RADIOFREQUENCY PLASMA POLYMERIZATION OF VINYLFERROCENE ON GLASSY-CARBON AND PLATINUM-ELECTRODES
    NOWAK, RJ
    SCHULTZ, FA
    UMANA, M
    LAM, R
    MURRAY, RW
    ANALYTICAL CHEMISTRY, 1980, 52 (02) : 315 - 321
  • [50] ELECTROCHEMICAL GENERATION OF POLYTHIOPHENE FILMS ON PLATINUM-ELECTRODES
    OTERO, TF
    DELARRETAAZELAIN, E
    POLYMER, 1988, 29 (08) : 1522 - 1527
12345