MAGNETIC AND ELECTRIC ANISOTROPY OF THE P=O AND P=S BONDS RELATIVE TO THE COTTON-MOUTON AND KERR EFFECTS

被引：0
|
作者：
VULFSON, SG
SARVAROVA, NN
NURETDINOVA, ON
机构：
[1] A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR
来源：
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1991年 / 40卷 / 03期
关键词：
D O I：
10.1007/BF00958013
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Cotton-Mouton and Kerr effects were used to determine the molecular magnetic and electric anisotropies of the hexamethyl triamides of phosphorous, phosphoric, and thiophosphoric acids. The anisotropies of the phosphoryl and thiophosphoryl groups were calculated. The magnetic anisotropies of these bonds depend on the immediate environment at the phosphorus atom and correlate linearly with the sigma-P reactivity constant.
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页码：647 / 649
页数：3
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