THE CHEMICAL NATURE OF INTERHALOGEN MOLECULES IN ICI AND IBR-GRAPHITE FROM I-27-MOSSBAUER AND I-129 MOSSBAUER-SPECTROSCOPY

被引：6
|
作者：
TIEDTKE, M
WORTMANN, G
机构：
[1] Fachbereich Physik, Freie Universität Berlin, Berlin 33
来源：
HYPERFINE INTERACTIONS | 1990年 / 53卷 / 1-4期
关键词：
D O I：
10.1007/BF02101077
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
The127I- and129I-Mössbauer resonances are applied to study the chemical nature of the interhalogen molecules ICI and IBr in stage-1 and stage-2 graphite intercalation compounds (GICs) and, for sake of comparison, in their solid molecular modifications. For both GIC systems one observes, in support of a model for the intercalate structure derived from recent X-ray absorption studies, two sites with an intensity ratio 1:1 and with similar isomer shifts and electric-quadrupole splittings. The charge transfer mechanisms are discussed in conjunction with complementary X-ray absorption and photoemission studies. © 1990 J.C. Baltzer AG, Scientific Publishing Company.
引用
收藏
页码：419 / 424
页数：6
相关论文
共 30 条
  • [21] SPECTROSCOPIC CHARACTERIZATION OF IODINE DOPED FLUOROGALLIUM(III) PORPHYRINS - DETERMINATION OF THE NATURE OF THE COUNTERION BY RAMAN AND I-129 MOSSBAUER SPECTROSCOPIES
    GUILARD, R
    BARBE, JM
    SANCHEZ, JP
    DAO, NQ
    INORGANICA CHIMICA ACTA, 1989, 164 (01) : 39 - 43
  • [22] ELECTRONIC AND MAGNETIC-PROPERTIES OF METAL DIIODIDES MI2 (M=V, CR, MN, FE, CO, NI, AND CD) FROM I-129 MOSSBAUER-SPECTROSCOPY
    FRIEDT, JM
    SANCHEZ, JP
    SHENOY, GK
    JOURNAL OF CHEMICAL PHYSICS, 1976, 65 (12): : 5093 - 5102
  • [23] STUDIES OF IBR ICL AND I2CL6 CRYSTAL PROPERTIES BY MEANS OF MOSSBAUER EFFECT IN 129I .I. CHEMICAL BONDS
    PASTERNA.M
    SONNINO, T
    JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (05): : 1997 - &
  • [24] STRUCTURAL, ELECTRONIC AND MAGNETIC-PROPERTIES OF THE LINEAR-CHAIN COMPOUNDS CSVI3, CSCRI3, CSMNI3 FROM I-129 MOSSBAUER-SPECTROSCOPY
    SANCHEZ, JP
    FRIEDT, JM
    DJERMOUNI, B
    JEHANNO, G
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1979, 40 (08) : 585 - 590
  • [25] MOLECULAR-STRUCTURE OF (AS2SE3)X(AS2TE3)1-X GLASSES - CHEMICAL EQUIVALENCE OF TE-125 ABSORPTION AND I-129 EMISSION MOSSBAUER-SPECTROSCOPY
    WELLS, J
    BOOLCHAND, P
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 1987, 89 (1-2) : 31 - 46
  • [26] MAGNETIC-PROPERTIES OF DYIR2SI2(I) FROM MOSSBAUER-SPECTROSCOPY AND MAGNETIZATION MEASUREMENTS
    TOMALA, K
    BLAISE, A
    KMIEC, R
    SANCHEZ, JP
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1992, 117 (1-2) : 275 - 284
  • [27] CHANGE IN NUCLEAR RADIUS UPON EXCITATION FOR SN-119, SB-121, TE-125, I-127, I-129, AND XE-129 FROM MOSSBAUER ISOMER SHIFTS
    RUBY, SL
    SHENOY, GK
    PHYSICAL REVIEW, 1969, 186 (02): : 326 - &
  • [28] CALIBRATION OF ISOMER-SHIFT AND QUADRUPOLE COUPLING FOR SN-119, I-127 AND I-129 AS DERIVED FROM SELF-CONSISTENT CHARGE X-ALPHA CALCULATIONS AND MOSSBAUER MEASUREMENTS
    GRODZICKI, M
    MANNING, V
    TRAUTWEIN, AX
    FRIEDT, JM
    JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1987, 20 (21) : 5595 - 5625
  • [29] A I-129 MOSSBAUER INVESTIGATION OF THE OHMIC CONTACT FORMATION MECHANISM IN THE AU/TE/AU/N-GAAS SYSTEM, QUESTIONED AND CONFIRMED BY X-RAY-ANALYSIS AND RAMAN-SPECTROSCOPY
    WUYTS, K
    WATTE, J
    VANDERSTRAETEN, H
    PATTYN, H
    LANGOUCHE, G
    SILVERANS, RE
    MUNDER, H
    BERGER, MG
    LUTH, H
    ZEGBE, G
    JUMAS, JC
    VANHOVE, M
    BENDER, H
    BORGHS, G
    VANROSSUM, M
    NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1992, 63 (1-2): : 141 - 146
  • [30] STRUCTURAL AND MAGNETIC-PROPERTIES OF N(C2H5)4FEI4 AND N(C4H9)4FEI4 FROM COMBINED FE-57 AND I-129 MOSSBAUER SPECTROSCOPIES
    FRIEDT, JM
    PETRIDIS, D
    SANCHEZ, JP
    RESCHKE, R
    TRAUTWEIN, A
    PHYSICAL REVIEW B, 1979, 19 (01): : 360 - 364
123