PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF K[ND(O-2,6-I-PR2C6H3)4] - A ONE-DIMENSIONAL CHAIN OF LANTHANIDE ARYLOXIDE ANIONS JOINED BY BIS(ETA-6-ARENE)-POTASSIUM INTERACTIONS

被引：69
|
作者：
CLARK, DL [1 ]
WATKIN, JG [1 ]
HUFFMAN, JC [1 ]
机构：
[1] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405
来源：
INORGANIC CHEMISTRY | 1992年 / 31卷 / 09期
关键词：
D O I：
10.1021/ic00035a006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of NdCl3 with 3 equiv of potassium 2,6-diisopropylphenoxide in THF solution forms the salt K[Nd(O-2,6-i-Pr2C6H3)4]. The [Nd(OAr)4-] anion is pseudotetrahedral, while the potassium cation displays a novel bis(eta(6)-arene) interaction with the arene rings of aryloxide ligands of adjacent anions, thereby forming an quasi-one-dimensional infinite chain structure. This example of a lanthanide infinite chain structure based upon a bis(eta(6)-arene)-alkali-metal interaction appears to be without precendent.
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页码：1554 / 1556
页数：3
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