[FCNF]+[ASF6]-, A SALT OF THE LINEAR 22-VALENCE ELECTRON CATION [FCNF]+

被引：7

作者：

TORNIEPORTHOETTING, IC ^{[1
]}

GOWIK, P ^{[1
]}

KLAPOTKE, TM ^{[1
]}

机构：

[1] TECH UNIV BERLIN,INST ANORGAN & ANALYT CHEM,STR 17 JUNI 135,W-1000 BERLIN 12,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 11期

关键词：

D O I：

10.1002/anie.199114851

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fluorination of the [HCNH]+ ion of 1 in hydrogen fluoride produces the 30-electron cation [FCNF]+ of 2. According to F-19 NMR and vibrational spectra this ion has a linear structure, which is in agreement with the predictions made by ab initio calculations. [HCNH]+/-[AsF6]- + 2F2 --> HF [FCNF]+/-[AsF6]- + 2HF

引用

页码：1485 / 1486

页数：2

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