[FCNF]+[ASF6]-, A SALT OF THE LINEAR 22-VALENCE ELECTRON CATION [FCNF]+

被引：7
|
作者：
TORNIEPORTHOETTING, IC [1 ]
GOWIK, P [1 ]
KLAPOTKE, TM [1 ]
机构：
[1] TECH UNIV BERLIN,INST ANORGAN & ANALYT CHEM,STR 17 JUNI 135,W-1000 BERLIN 12,GERMANY
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 11期
关键词：
D O I：
10.1002/anie.199114851
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Fluorination of the [HCNH]+ ion of 1 in hydrogen fluoride produces the 30-electron cation [FCNF]+ of 2. According to F-19 NMR and vibrational spectra this ion has a linear structure, which is in agreement with the predictions made by ab initio calculations. [HCNH]+/-[AsF6]- + 2F2 --> HF [FCNF]+/-[AsF6]- + 2HF
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页码：1485 / 1486
页数：2
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