CONVENIENT SYNTHESIS OF WATER-SOLUBLE, ISOMERICALLY PURE RUTHENIUM PHTHALOCYANINE COMPLEXES

被引：38

作者：

BOSSARD, GE ^{[1
]}

ABRAMS, MJ ^{[1
]}

DARKES, MC ^{[1
]}

VOLLANO, JF ^{[1
]}

BROOKS, RC ^{[1
]}

机构：

[1] JOHNSON MATTHEY BIOMED RES,W CHESTER,PA 19380

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 06期

关键词：

D O I：

10.1021/ic00110a034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A simple high-yielding synthesis of water soluble ruthenium phthalocyanine complexes, (Pc)RuL(2), is reported. Use of an unsubstituted or symmetrically substituted phthalocyanine ring and solubilizing ligands axially coordinated to the central ruthenium allowed pure compounds, without positional isomers, to be made, Key to the success of the synthesis is the use of a soluble (Pc)RuL(2) intermediate with labile nitrile axial ligands that could be easily and completely substituted. A range of axial ligands was introduced into the (Pc)Ru moiety including pyridines, alkyl amines. amino acids, and phosphines.

引用

页码：1524 / 1527

页数：4

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