KINETIC AND EQUILIBRIUM STUDIES OF THE REACTION OF 1-X-2,4,6-TRINITROBENZENES WITH PENTAISOPROPYLGUANIDINE IN ACETONITRILE

被引：0

作者：

SCHROEDER, G

PRZYBYL, J

LESKA, B

机构：

来源：

POLISH JOURNAL OF CHEMISTRY | 1993年 / 67卷 / 02期

关键词：

SIGMA-COMPLEX; PROTON TRANSFER REACTION; PENTAISOPROPYLGUANIDINE; KINETIC REACTION;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetic and equilibrium measurements are reported for the reactions of 1-X-2,4,6-trinitrobenzenes (X = H, Me, Et, iPr) with pentaisopropylguanidine in acetonitrile. For X=H and iPr only sigma complex formation was observed whereas for X=Me and Et we observed two products: sigma complex and conjugate base. The rate and equilibrium constants, activation and reaction parameters for sigma complex formation and the proton transfer reaction are discussed.

引用

页码：273 / 280

页数：8

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