OXIDATION OF ALLYLIC ALCOHOLS BY DIMETHYLDIOXIRANE - COMPETITION REACTION BETWEEN EPOXIDATION AND C-H INSERTION

被引：25
|
作者：
ADAM, W
PRECHTL, F
RICHTER, MJ
SMERZ, AK
机构：
[1] Institute of Organic Chemistry, University of Würzburg, D-97074 Würzburg, Am Hubland
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 52期
关键词：
D O I：
10.1016/S0040-4039(00)61350-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Epoxidation of allylic alcohols with dimethyldioxirane is accompanied by oxidation of the hydroxy functionality; thus enone formation increases with decreasing substitution at the C-C double bond; nonetheless, selective epoxidation can be obtained by acylation of the alcohol functionality.
引用
收藏
页码：8427 / 8430
页数：4
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