THE VIBRATIONAL-SPECTRA OF A SIMPLE PEROXIDE - FC(O)OOC(O)F

被引：6
|
作者：
DELLAVEDOVA, CO [1 ]
MACK, HG [1 ]
机构：
[1] UNIV TUBINGEN,INST PHYS & THEORET CHEM,W-7400 TUBINGEN 1,GERMANY
来源：
JOURNAL OF MOLECULAR STRUCTURE | 1992年 / 274卷
关键词：
D O I：
10.1016/0022-2860(92)80143-6
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Vibrational data for gaseous, liquid and matrix-isolated bis(fluorocarbonyl) peroxide, FC(O)OOC(O)F, were obtained and the photochemical behaviour of the substance conveniently isolated in a noble gas matrix was investigated. The interpretation of the data indicated a skew structure (C2 symmetry) with the C-F single bonds trans to the O-O single bond.
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页码：25 / 32
页数：8
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